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• W1988152885 abstract "Different diglycolamide (DGA)-substituted calix[4]arene-based extractants were synthesized and evaluated for the extraction of Am(III) and Eu(III), representative trivalent actinide and lanthanide ions, respectively. On the narrow rim of the calix[4]arene platform, the DGA moiety was either 1,3-di- or tetrasubstituted with a varying spacer length between the oxygen and amide nitrogen atom. In addition, DGA groups were appended both to the wide rim and to both rims of calix[4]arenes and their efficiencies were compared for Am(III) and Eu(III) extraction at three different feed acidities. The extraction and separation efficiencies strongly depended on the N-alkyl substituent as well as the spacer length. 1,3-Di-DGA-substituted calix[4]arenes are inferior extractants to the corresponding tetra-DGA-substituted ones. Narrow rim DGA-functionalized derivatives resulted in high extraction efficiencies, while the wide rim DGA-functionalized calix[4]arenes showed practically no extraction." @default.
• W1988152885 created "2016-06-24" @default.
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• W1988152885 date "2012-09-01" @default.
• W1988152885 modified "2023-09-26" @default.
• W1988152885 title "Preorganization of diglycolamides on the calix[4]arene platform and its effect on the extraction of Am(III)/Eu(III)" @default.
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• W1988152885 doi "https://doi.org/10.1016/j.tet.2012.07.036" @default.
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