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- W1988196802 abstract "Both spatial and temporal peaks that are produced by the discrete parcel model can be mathematically approximated by Gaussian functions, but the transformation from a spatial pattern to a temporal image requires a convolution treatment. A first-order convolution is given for temporal peaks under a linear isotherm, whereas a second-order convolution is proposed for those under non-linear isotherms. Numerical tests show that the peak shapes generated by the proposed temporally convoluted Gaussian equations (TCG) match perfectly with those obtained by the discrete parcel model. Although the full TCG equation may be quite complicated, it can be made easier by a recursion calculation technique, and a group of peak curves can be plotted simultaneously on computer worksheet. The results also suggest that the temporal distortion effect should be predominately considered, in addition to those known-to-exist spatial effects, for explaining the peak asymmetry." @default.
- W1988196802 created "2016-06-24" @default.
- W1988196802 creator A5082872064 @default.
- W1988196802 date "2004-02-01" @default.
- W1988196802 modified "2023-09-27" @default.
- W1988196802 title "Temporally convoluted Gaussian equations for chromatographic peaks" @default.
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- W1988196802 doi "https://doi.org/10.1016/j.chroma.2003.11.091" @default.
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