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- W1988273642 abstract "Reaction of (R,R)-(−)- and (S,S)-(+)-1,2-bis(pyrrol-2-ylmethyleneamino)cyclohexane with K2PtCl4 afforded chiral, neutral platinum(II) Schiff base complexes of (R,R)-PtL and (S,S)-PtL with high yields. The rare C–H⋯Pt(II) intermolecular interaction was found to show considerable strength and directionality for controlling M and P helical supramolecular architectures of (R,R)-PtL and (S,S)-PtL, respectively, in crystal lattices. More importantly, the open square-planar geometry of platinum(II) complexes allows axial C–H⋯Pt(II) interaction, resulting in the 3(ππ∗) excited state with some mixing of the Pt(II) metal character observed both in concentrated solutions and in the solid state at room temperature." @default.
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- W1988273642 date "2008-06-01" @default.
- W1988273642 modified "2023-10-14" @default.
- W1988273642 title "C–H⋯Pt(II) interaction-controlled self-assembly and photophysics of chiral bis(pyrrol-2-ylmethyleneamino)cyclohexane platinum(II) complexes" @default.
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- W1988273642 doi "https://doi.org/10.1016/j.tet.2008.03.077" @default.
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