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- W1988361981 abstract "Vinyl ethers selectively undergo the combined C-H functionalization/Cope rearrangement reaction via an s-cis/boat transition state. With chiral dirhodium catalysts, products are generated in a highly diastereoselective and enantioselective fashion. This reaction can be considered as a surrogate to the traditional vinylogous Mukaiyama aldol reaction. Effective kinetic resolution has been achieved, leading to the recovery of a cyclic vinyl ether with axial chirality of high enantiomeric purity." @default.
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- W1988361981 date "2011-07-18" @default.
- W1988361981 modified "2023-10-05" @default.
- W1988361981 title "Combined C–H Functionalization/Cope Rearrangement with Vinyl Ethers as a Surrogate for the Vinylogous Mukaiyama Aldol Reaction" @default.
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- W1988361981 doi "https://doi.org/10.1021/ja2051155" @default.
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