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- W1988367639 abstract "Cu2ZnSn(S1−xSex)4 nanocrystals are an emerging family of functional materials with huge potential of industrial applications, however, it is an extremely challenging task to synthesize Cu2ZnSn(S1−xSex)4 nanocrystals with both tunable energy band and phase purity. Here we show that a green and economic route could be designed for the synthesis of Cu2ZnSn(S1−xSex)4 nanocrystals with bandgap tunable in the range of 1.5–1.12 eV. Consequently, conduction band edge shifted from −3.9 eV to −4.61 eV (relative to vacuum energy) is realized. The phase purity of Cu2ZnSn(S1−xSex)4 nanocrystals is substantiated with in-depth combined optical and structural characterizations. Electrocatalytic and thermoelectric performances of Cu2ZnSn(S1−xSex)4 nanocrystals verify their superior activity to replace noble metal Pt and materials containing heavy metals. This green and economic route will promote large-scale application of Cu2ZnSn(S1−xSex)4 nanocrystals as solar cell materials, electrocatalysts and thermoelectric materials." @default.
- W1988367639 created "2016-06-24" @default.
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- W1988367639 date "2013-09-24" @default.
- W1988367639 modified "2023-10-18" @default.
- W1988367639 title "A Route to Phase Controllable Cu2ZnSn(S1−xSex)4 Nanocrystals with Tunable Energy Bands" @default.
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- W1988367639 doi "https://doi.org/10.1038/srep02733" @default.
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