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- W1988377029 abstract "Interaction of ammonium salt of N-isonicotinamidosalicylaldimine (H2sal-inh) and N-(2-hydroxyphenyl)salicylideneamine (H2sal-oap) with NH4VO3 inserted in Na–Y zeolite in aqueous solution at pH ca. 7.5 leads to the formation of dioxovanadium(V) complexes in the super cages of the zeolite–Y. These encapsulated complexes exhibit good catalytic activity towards the oxidative bromination of salicylaldehyde using H2O2 as an oxidant in presence of KBr; a reaction similar to that exhibited by vanadate-dependent haloperoxidases (V-HalPO). Under the reaction conditions the percent formation of a major product 5-bromosalicylaldehyde follows the order: NH4[VO2(sal-inh)]–Y (34%) > NH4[VO2(sal-oap)]–Y (26.8%) > Na/NH4VO3–Y (22%) with ca. 87% selectivity after 4 h of reaction time. These encapsulated complexes do not leach or decompose during catalytic activity study, showing their practical utility over free complexes." @default.
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- W1988377029 date "2004-10-01" @default.
- W1988377029 modified "2023-10-14" @default.
- W1988377029 title "Oxidative bromination of salicylaldehyde by potassium bromide/H2O2 catalysed by dioxovanadium(V) complexes encapsulated in zeolite–Y: a functional model of haloperoxidases" @default.
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- W1988377029 doi "https://doi.org/10.1016/j.catcom.2004.07.004" @default.
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