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- W1988380167 abstract "Heats of mixing have been obtained at 25° for the following mixtures of linear methylsiloxanes : hexamethyldisiloxane (dimer)-octamethyltrisiloxane (trimer); dimer-tetramer; dimer-pentamer; trimer-pentamer and dimer-polymer. The heats are consistent with the Prigogine cell theory for the thermodynamics of chain-molecule mixtures and with Brϕnsted's principle of congruence. Two assumptions concerning the volume dependence of the configurational energy of a liquid were tested : that of a van der Waals liquid which gave good results and a 6-12 model which gave poor results. Two excess volume results were also in accord with the former model. The relation between the Prigogine cell theory and the recent theory of Flory, Orwoll and Vrij is examined." @default.
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- W1988380167 date "1968-01-01" @default.
- W1988380167 modified "2023-10-16" @default.
- W1988380167 title "Thermodynamics of chain-molecule mixtures : heats of mixing of linear methylsiloxanes" @default.
- W1988380167 doi "https://doi.org/10.1039/tf9686400648" @default.
- W1988380167 hasPublicationYear "1968" @default.
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