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- W1988390880 abstract "The half-wave potentials, corresponding to irreversible two-electron transfers, were determined for the electroreduction of substituted chloro- and bromobenzenes in a number of organic solvents. In each solvent they obey the Hammett equation, and the reaction constants ϱ, found for each series are solvent dependent. Since the first electron transfer is the rate-determining step for the overall process and the irreversible half-wave potentials depend on the heterogeneous rate constants, it is shown that the ϱ values obtained are linear functions of the logarithms of the solvent longitudinal relaxation times. This is the first example indicating the role of solvent relaxation dynamics in irreversible electrode processes accompanied by bond cleavage. Differences in the Hammett behaviour obtained and that described by us previously for the reduction of substituted iodobenzenes are discussed on the basis of a mechanism of electrode processes." @default.
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- W1988390880 date "1993-11-01" @default.
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- W1988390880 title "Hammett reaction constants for the electroreduction of substituted chloro- and bromobenzenes: Effect of solvent dynamics on the two-electron irreversible reductive cleavage" @default.
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- W1988390880 doi "https://doi.org/10.1016/0022-0728(93)80439-o" @default.
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