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- W1988402470 abstract "Qualitative analyses of bandshapes of molecular aggregates are made in terms of hypochromism (or hyperchromism) taking account of the TRK sum rule. The linear response theory for vibronic systems is applied to the analyses for the sharp J-band and the bands of the DNA-dye complexes as examples. It is numerically checked that the sum rule is satisfied within the absorption region under consideration. It is also emphasized that a particular bandshape in the region of interest is governed by not only its neighboring electronic levels but also by higher electronic levels outside the absorption region - this fact being implicated by the TRK sum rule. Finally, an analytical relationship for the bandwidths of polymer vibronic bands which are to be determined entirely by intermolecular interaction is derived and discussed in connection with the damping parameters." @default.
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- W1988402470 date "1975-04-01" @default.
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- W1988402470 title "Bandshapes of electronic absorption spectra in molecular aggregates" @default.
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- W1988402470 doi "https://doi.org/10.1016/0301-0104(75)80095-4" @default.
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