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- W1988455849 abstract "The title complex undergoes decomposition in acidic aqueous solution resulting in equimolar concentration of aquapentaamminecobalt(III) and hexa- aquacobalt(II). The kinetic studies over the ranges of 0.048 M ⩽ [H+] ⩽ 0.385 M, 25 ⩽ θc ⩽ 41.5°C and at I = 0.5 M reveals that the intricate mechanism involves protonation equilibrium of the title complex, followed by a rate determining bridge cleavage. The further follow-up reaction is a fast electron transfer process to form products. The rate expression derived from the mechanism is kobs = k1K1[H+]/(1 + K1[H+]) where the values of k, and K, are found to be 8.9 × 10−4 s−1 and 3.5 M−1 respectively at 25 °C. The results are compared with that obtained for the decomposition reactions of mononuclear aquaammine complexes of cobalt(III)." @default.
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- W1988455849 date "1988-02-01" @default.
- W1988455849 modified "2023-09-27" @default.
- W1988455849 title "Kinetics and mechanism of the decomposition of μ-amido-μ-hydroxo(tetraamminecobalt(III))(tetraaquacobalt(III)) ion in acidic aqueous solution" @default.
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- W1988455849 doi "https://doi.org/10.1016/s0020-1693(00)80653-2" @default.
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