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- W1988479978 abstract "Die Polarographie der heterocyclischen Redoxsysteme 6–10, 14 und 15 zeigt reversible zweistufige Einelektronenübergänge mit Semichinonbildungskonstanten K ≈︁ 107–1010 (6–10) bzw. ≈︁ 104 (14) und 120 (15) [Abbildung 6]. Der Substituenteneinfluß auf K und die Lage der Potentiale werden besprochen. Die Elektronenspektren von 6–10, 14 und 15 in ihren Oxydationsstufen RED, SEM und OX werden verglichen (Tabelle 3). Two-step Redox Systems, VII1). Polarography and Spectroscopy of Heterocyclic Azines and their Higher Oxidation Levels The polarography of the heterocyclic redox systems 6–10, 14 and 15 reveals reversible one-electron transfers in two steps. Semiquinone formation constants K are ≈︁ 107–1010 (6–10), ≈︁ 104 (14) and 120 (15) [figure 6]. The influence of substituents on K and the position of the potentials are discussed. Electron spectra of 6–10, 14 and 15 on the oxidation levels RED, SEM and OX are compared (table 3)." @default.
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- W1988479978 date "1971-10-29" @default.
- W1988479978 modified "2023-10-16" @default.
- W1988479978 title "über zweistufige Redoxsysteme, VII. Polarographie und Spektroskopie heterocyclischer Azine und ihrer höheren Oxydationsstufen" @default.
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- W1988479978 doi "https://doi.org/10.1002/jlac.19717520121" @default.
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