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- W1988506568 abstract "Abstract This report describes a facile route to prepare the vesicles and large compound micelles (LCMs) from a series of poly( ε ‐benzyloxycarbonyl L ‐lysine)‐ block ‐poly[diethylene glycol bis (3‐amino propyl) ether]‐ block ‐poly( ε ‐benzyloxycarbonyl L ‐lysine) (PZLL‐DGBE‐PZLL) in their water solution, depending on molecular weight of the polypeptides. A pyrene probe is used to demonstrate the aggregate formation of PZLL‐DGBE‐PZLL in solution, and also to measure their critical micelle concentration as a function of molecular weight of the polymer. Transmission electron microscopy, atomic force microscopy, dynamic light scattering and confocal laser scanning microscopy are used to observe their aggregate morphologies. Rhodamine B is used as a fluorescent probe to confirm the structure of large compound micelles composed of many reverse micelles with aqueous cores. These polypeptides are prepared by ring‐opening polymerization of α ‐amino acid N ‐carboxyanhydrides with a small molecule as the initiator. Their structures are confirmed by NMR and SEC‐MALLS. These vesicles and large compound micelles are extremely expected to be used in drug delivery. magnified image" @default.
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- W1988506568 date "2008-05-26" @default.
- W1988506568 modified "2023-10-14" @default.
- W1988506568 title "Self-Assembly of a Hydrophobic Polypeptide Containing a Short Hydrophilic Middle Segment: Vesicles to Large Compound Micelles" @default.
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- W1988506568 doi "https://doi.org/10.1002/macp.200800018" @default.
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