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- W1988533240 abstract "Since the discovery of the anomalous dispersion of a-helical polypeptidesl, 2 and the introduction of the Moffitt equation,3 4 ORD has been applied extensively to conformational studies of proteins and polypeptides. Although the early theories'3 5 were unsatisfactory,6 we do not yet have a relationship as simple as Moffitt's to describe ORD in the visible region. Instrumental limitation confined almost all early experimental data to wavelengths above 300 my. Now that measurements can be extended to about 185 mn, we detect conformation-dependent Cotton effects7' s (and CD9) between 180 and 240 my. It seems desirable to re-evaluate ORD analysis in the visible region. All treatments proposed are phenomenological, and success should be tempered with caution in interpreting the experimental results quantitatively or semiquantitatively. The illoffitt Equation.-Moffitt's equation3 4" @default.
- W1988533240 created "2016-06-24" @default.
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- W1988533240 date "1965-02-01" @default.
- W1988533240 modified "2023-09-23" @default.
- W1988533240 title "ON THE PHENOMENOLOGICAL TREATMENTS OF OPTICAL ROTATORY DISPERSION OF POLYPEPTIDES AND PROTEINS" @default.
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- W1988533240 doi "https://doi.org/10.1073/pnas.53.2.438" @default.
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