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- W1988551034 abstract "N-Demethylation is a key step in the preparation of a number of semisynthetic opiate pharmaceuticals. Herein we report a high-yielding, catalytic procedure for the N-demethylation of opiates which has a number of advantages over existing methods. For example, tetrasodium 5,10,15,20-tetra(4-sulfophenyl)porphyrinatoiron(II) (0.3 molar equiv) effected the transformation of codeine methyl ether to the corresponding N-nor analogue in 91% yield. The catalyst was readily removed and recycled." @default.
- W1988551034 created "2016-06-24" @default.
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- W1988551034 date "2007-11-17" @default.
- W1988551034 modified "2023-09-25" @default.
- W1988551034 title "New Methodology for the N-Demethylation of Opiate Alkaloids" @default.
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- W1988551034 doi "https://doi.org/10.1021/jo071171q" @default.
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