FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1988551036> ?p ?o ?g. }

• W1988551036 endingPage "300" @default.
• W1988551036 startingPage "289" @default.
• W1988551036 abstract "The previously revised Freed lattice model is used to replace the Flory-Huggins mean-field theory for binary polymer/solvent mixtures. Liquid-liquid binodals calculated for model systems are in good agreement with those from computer simulation and those from Freed's rigorous lattice cluster theory. A double lattice model is used to account for oriented interactions such as hydrogen bonding. To account for free-volume effects, an essentially empirical, two-step process is adopted. First, pure components are mixed to form a close-packed polymer solution. Then, holes are Introduced to mix with the close-packed solution which is considered to be a pseudo-pure substance. The revised Freed model is applied for both steps. A size parameter Cr accounts for the composition dependence of effective chain lengths. Two binary energy parameters are used: ϵ is the conventional interchange energy of a nearest-neighbor i-J segment-segment pair, and ξ corrects the quadratic rule for mixing the two components to form a pseudo-pure substance. Pure-component parameters, Γio and ϵii, are obtained by fitting experimental pure-component vapor pressure and pVT data. A few examples indicate that the semi -empirical model can describe satisfactorily a variety of liquid-liquid equilibria Including UCST, LCST, XXXiscibility-loop and hour-glass-shaped phase diagrams, as well as the pressure dependence and the molar-mass dependence of liquid-liquid binodals." @default.
• W1988551036 created "2016-06-24" @default.
• W1988551036 creator A5020540558 @default.
• W1988551036 creator A5025351275 @default.
• W1988551036 creator A5033680548 @default.
• W1988551036 creator A5062775963 @default.
• W1988551036 date "1993-02-01" @default.
• W1988551036 modified "2023-10-18" @default.
• W1988551036 title "Molecular thermodynamics of polymer solutions" @default.
• W1988551036 cites W1970080655 @default.
• W1988551036 cites W1975262077 @default.
• W1988551036 cites W1982610073 @default.
• W1988551036 cites W1990243289 @default.
• W1988551036 cites W1992038834 @default.
• W1988551036 cites W1993358972 @default.
• W1988551036 cites W1994227031 @default.
• W1988551036 cites W1997373424 @default.
• W1988551036 cites W2008368175 @default.
• W1988551036 cites W2008669501 @default.
• W1988551036 cites W2011719641 @default.
• W1988551036 cites W2016503547 @default.
• W1988551036 cites W2022075976 @default.
• W1988551036 cites W2039134848 @default.
• W1988551036 cites W2059652945 @default.
• W1988551036 cites W2060883143 @default.
• W1988551036 cites W2060980599 @default.
• W1988551036 cites W2063522472 @default.
• W1988551036 cites W2066118588 @default.
• W1988551036 cites W2067992397 @default.
• W1988551036 cites W2078723406 @default.
• W1988551036 cites W2079966579 @default.
• W1988551036 cites W2089176522 @default.
• W1988551036 cites W2093448331 @default.
• W1988551036 cites W2126979837 @default.
• W1988551036 cites W2166295771 @default.
• W1988551036 cites W2325022774 @default.
• W1988551036 cites W2334446098 @default.
• W1988551036 cites W2335752349 @default.
• W1988551036 cites W4231546251 @default.
• W1988551036 doi "https://doi.org/10.1016/0378-3812(93)87032-v" @default.
• W1988551036 hasPublicationYear "1993" @default.
• W1988551036 type Work @default.
• W1988551036 sameAs 1988551036 @default.
• W1988551036 citedByCount "38" @default.
• W1988551036 countsByYear W19885510362012 @default.
• W1988551036 countsByYear W19885510362013 @default.
• W1988551036 countsByYear W19885510362014 @default.
• W1988551036 countsByYear W19885510362021 @default.
• W1988551036 crossrefType "journal-article" @default.
• W1988551036 hasAuthorship W1988551036A5020540558 @default.
• W1988551036 hasAuthorship W1988551036A5025351275 @default.
• W1988551036 hasAuthorship W1988551036A5033680548 @default.
• W1988551036 hasAuthorship W1988551036A5062775963 @default.
• W1988551036 hasConcept C121332964 @default.
• W1988551036 hasConcept C121864883 @default.
• W1988551036 hasConcept C131847037 @default.
• W1988551036 hasConcept C15920480 @default.
• W1988551036 hasConcept C178790620 @default.
• W1988551036 hasConcept C185592680 @default.
• W1988551036 hasConcept C188109995 @default.
• W1988551036 hasConcept C24890656 @default.
• W1988551036 hasConcept C2781204021 @default.
• W1988551036 hasConcept C33923547 @default.
• W1988551036 hasConcept C44280652 @default.
• W1988551036 hasConcept C48372109 @default.
• W1988551036 hasConcept C521977710 @default.
• W1988551036 hasConcept C85906118 @default.
• W1988551036 hasConcept C94375191 @default.
• W1988551036 hasConcept C97355855 @default.
• W1988551036 hasConcept C98765843 @default.
• W1988551036 hasConceptScore W1988551036C121332964 @default.
• W1988551036 hasConceptScore W1988551036C121864883 @default.
• W1988551036 hasConceptScore W1988551036C131847037 @default.
• W1988551036 hasConceptScore W1988551036C15920480 @default.
• W1988551036 hasConceptScore W1988551036C178790620 @default.
• W1988551036 hasConceptScore W1988551036C185592680 @default.
• W1988551036 hasConceptScore W1988551036C188109995 @default.
• W1988551036 hasConceptScore W1988551036C24890656 @default.
• W1988551036 hasConceptScore W1988551036C2781204021 @default.
• W1988551036 hasConceptScore W1988551036C33923547 @default.
• W1988551036 hasConceptScore W1988551036C44280652 @default.
• W1988551036 hasConceptScore W1988551036C48372109 @default.
• W1988551036 hasConceptScore W1988551036C521977710 @default.
• W1988551036 hasConceptScore W1988551036C85906118 @default.
• W1988551036 hasConceptScore W1988551036C94375191 @default.
• W1988551036 hasConceptScore W1988551036C97355855 @default.
• W1988551036 hasConceptScore W1988551036C98765843 @default.
• W1988551036 hasLocation W19885510361 @default.
• W1988551036 hasOpenAccess W1988551036 @default.
• W1988551036 hasPrimaryLocation W19885510361 @default.
• W1988551036 hasRelatedWork W1970647586 @default.
• W1988551036 hasRelatedWork W1976337186 @default.
• W1988551036 hasRelatedWork W1997243805 @default.
• W1988551036 hasRelatedWork W2012629179 @default.
• W1988551036 hasRelatedWork W2027287801 @default.
• W1988551036 hasRelatedWork W2032361468 @default.
• W1988551036 hasRelatedWork W2049398285 @default.
• W1988551036 hasRelatedWork W2072171428 @default.

• next