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• W1988556491 endingPage "1956" @default.
• W1988556491 startingPage "1947" @default.
• W1988556491 abstract "Improvements of XAFS (X-Ray Absorption Fine Structure) measurements in the time domain are summarized and several examples of structure determination of reaction intermediates by the EXAFS (Extended X-Ray Absorption Fine Structure) method are given. The local structure around the copper(II) or cobalt(II) ion is described in the reaction intermediate in the metal substitution reaction of the homodinuclear mercury(II) porphyrinato (5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin; H6tpps) complex in an acetate buffer determined by the stopped-flow EXAFS (SF-EXAFS) method, which was developed by us. Comparison of the bond lengths in the intermediates with those in the reactants and the products of the metal substitution reaction, the structure of which has been determined by the same method, revealed the cause of the instability of the reaction intermediates." @default.
• W1988556491 created "2016-06-24" @default.
• W1988556491 creator A5042516411 @default.
• W1988556491 creator A5074918548 @default.
• W1988556491 date "1999-09-01" @default.
• W1988556491 modified "2023-10-14" @default.
• W1988556491 title "Structure Analysis of Reaction Intermediates in Metal Substitution Reactions in Solution by the Stopped-Flow EXAFS Method" @default.
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• W1988556491 doi "https://doi.org/10.1246/bcsj.72.1947" @default.
• W1988556491 hasPublicationYear "1999" @default.
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