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• W1988597562 abstract "Abstract Thorium- and uranium-ligand bond disruption enthalpies ( D (AnR)) have been obtained for the series of complexes Ind 3 AnR, where Ind  C 9 H 7 or 1-C 2 H 5 C 9 H 6 , An  Th or U, R = an alkyl group. All the new compounds have been characterised by microanalysis and spectroscopy. The thermodynamic data were determined by oxygen-free batch-titration, solution calorimetry from the enthalpies of solution of the organo- f -element complexes in toluene and from the subsequent enthalpies of alcoholysis with 2,2,2-trifluoroethanol. D (An) gas values obtained (95% of confidence) were as follows: (C 9 H 7 ) 3 ThCH 2 Si(CH 3 ) 3 , (397 ± 7) kJ mol −1 ; (C 9 H 7 ) 3 ThCH 3 , (371 ± 6) kJ mol −1 ; (1-C 2 H 5 C 9 H 6 ) 3 ThCH 3 , (365 ± 5) kJ mol −1 ; (C 9 H 7 ) 3 ThCH(CH 3 ) 2 , (357 ± 8) kJ mol −1 ; (C 9 H 7 ) 3 UCH 3 , (351 ± 2) kJ mol −1 ; (1-C 2 H 5 C 9 H 6 ) 3 UCH 3 , (350 ± 4) kJ mol −1 and (C 9 H 7 ) 3 ThCH 2 C 6 H 5 , (342 ± 9) kJ mol −1 . These bond disruption enthalpies parallel, but are significantly larger than, those for the identical R functionalities in the (C 5 H 5 ) 3 ThR series. For corresponding Th/U pairs, the difference { D (ThR) − D (UR)} is ca. 20 kJ mol −1 ." @default.
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• W1988597562 date "1989-11-01" @default.
• W1988597562 modified "2023-09-23" @default.
• W1988597562 title "Organo-f-element thermochemistry. Actinide-ligand bond disruption enthalpies in tris(indenyl)actinide hydrocarbyls" @default.
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• W1988597562 doi "https://doi.org/10.1016/0022-328x(89)80051-8" @default.
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