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- W1988603939 abstract "We first found experimentally a cycloaddition reaction of a molecule on a symmetry Si pair, 1,3-butadiene on the Si adatom pair of Si(111)7x7, while up to now only asymmetric Si pairs were reported to be involved in cycloaddition reactions on Si surfaces. As the symmetry of a Si pair is expected to influence significantly a cycloaddition product and a reaction pathway, the [4+2]-like cycloaddition product of 1,3-butadiene on the Si adatom pair is suggested to form through a concerted reaction pathway in comparison to a stepwise reaction pathway, which is favorable in the formation of the [4+2]-like cycloaddition product on the asymmetric Si pair (the Si adatom-restatom pair)." @default.
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- W1988603939 date "2006-06-13" @default.
- W1988603939 modified "2023-10-16" @default.
- W1988603939 title "Cycloaddition Reaction of 1,3-Butadiene with a Symmetric Si Adatom Pair on the Si(111)7×7 Surface" @default.
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- W1988603939 doi "https://doi.org/10.1021/ja0600072" @default.
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