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- W1988652010 abstract "The retinal analogues (13Z)-13-bromo-13-desmethylretinal (3) and (13E)-20,20,20-trifluororetinal (4) have been efficiently synthesized using the palladium-catalyzed cross-coupling of boronic acid 8 and electrophiles 9 and 10, respectively. For the first analogue, the coupling of 8 and the gem-dibromide 9 took place with high stereoselectivity. The configuration of the C13-C14 double bond in 4 relied on the stereoselective preparation and coupling of alkenyltriflate Z-10 from β-ketoester 15." @default.
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- W1988652010 date "1999-11-01" @default.
- W1988652010 modified "2023-10-15" @default.
- W1988652010 title "Stereocontrolled synthesis of retinoids functionalized at C-13 by suzuki coupling reactions" @default.
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- W1988652010 doi "https://doi.org/10.1016/s0040-4020(99)00861-3" @default.
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