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- W1988686397 abstract "In the ternary system of rare earth-cobalt-boron, RCo3B2 compounds (R=rare earth elements) were prepared by arc-melting methods. Their crystal structure was investigated by X-ray diffraction methods. These ternary borides, RCo3B2, crystallize in a hexagonal lattice. The lattice parameters are a=5.020±0.002 A and c=3.027±0.002 A for YCo3B2 and a=5.066±0.003 A and c=3.022±0.002 A for GdCo3B2. The good agreement between the X-ray diffraction intensities observed and calculated shows that the ternary borides, YCo3B2 and GdCo3B2, crystallize in the CaZn5-type structure. The space group and atomic positions are as follows: P6/mmm (D6h1), 1R in 1(a), 3Co in 3(g), and 2B in 2(c). It can be seen from these results that the ternary borides, RCo3B2, have a superstructure in which two Co atoms in the 2(c) site of intermetallic compounds, RCo5, with the CaZn5-type structure are replaced by two B atoms. The B atoms in this structure are situated at the center of a trigonal prism formed by six Co atoms. The interatomic ..." @default.
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- W1988686397 date "1973-03-01" @default.
- W1988686397 modified "2023-10-18" @default.
- W1988686397 title "The Preparation and Crystal Structure of Ternary Rare Earth Borides, RCo<sub>3</sub>B<sub>2</sub>" @default.
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- W1988686397 doi "https://doi.org/10.1246/bcsj.46.770" @default.
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