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• W1988706573 abstract "Calixarenes bridged by thia (−S−), sulfinyl (−SO−), or sulfonyl (−SO2−) linkers have been employed as ancillary ligands in vanadium-based ethylene polymerization and in the ring-opening polymerization of ε-caprolactone. For ethylene polymerization, all pro-catalysts [PPh4][VOCl2(R-calix[4]areneH2)] (R = p-tert-butylthia (−S−) (1), sulfinyl (−SO−) (2), sulfonyl (−SO2−) (3)) were highly active, with the system bearing the sulfonyl (−SO2−)-bridged calixarene displaying enhanced activity. The molecular structures of pro-catalysts 2 and 3 are reported. Pro-catalysts 1–3 were inactive for the ROP of ε-caprolactone." @default.
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• W1988706573 date "2011-10-14" @default.
• W1988706573 modified "2023-09-27" @default.
• W1988706573 title "Ethylene Polymerization Catalysis by Vanadium-Based Systems Bearing Sulfur-Bridged Calixarenes" @default.
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• W1988706573 doi "https://doi.org/10.1021/om200402u" @default.
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