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- W1988753756 abstract "The effect of proton ordering in tetrahydrofuran hydrate is detected using a technique based on measurement of thermal conductivity. The thermal conductivity of tetrahydrofuran hydrate is measured by the steady-state potentiometric method in the interval 2–150K. Two regimes are selected to observe the effect: (i) slow cooling of the hydrate sample, and (ii) doping of the hydrate with a small quantity of KOH alkali to a concentration of 10−4. Proton ordering affects the temperature dependence of the thermal conductivity, changing its glass-like behavior to crystal-like below 150K. The phonon maximum that appears in the temperature dependence of the thermal conductivity at T=17K is attributed to the cooperative process of local proton ordering stimulated by orientational and ionic defects." @default.
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- W1988753756 date "2008-08-01" @default.
- W1988753756 modified "2023-10-18" @default.
- W1988753756 title "The effect of proton ordering on the thermal conductivity of clathrate tetrahydrofuran hydrate" @default.
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- W1988753756 doi "https://doi.org/10.1063/1.2967511" @default.
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