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• W1988766686 endingPage "131" @default.
• W1988766686 startingPage "121" @default.
• W1988766686 abstract "Gas-phase electron diffraction experiments have been carried out on NO2 at three temperatures, viz., 294, 480, and 691 K. Applying the necessary vibrational corrections, the equilibrium structure (re) of NO2 was determined from the 480 K data where it was the sole component of the vapor, 1.195(3) Å and 133.7(2)∘. This information was then utilized in the analysis of the mixture of NO2 (82%) and N2O4 (18%) at 294 K. The NO bond of NO2 is shorter than that of N2O4 by 0.008 Å, and the ONO angle opens slightly in the dimer as compared with NO2. The barrier height to internal rotation in N2O4 is estimated to be about 40 kJ mol−1 from the electron diffraction data. There is a slight increase of the average NO bond length (rg) at higher temperatures." @default.
• W1988766686 created "2016-06-24" @default.
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• W1988766686 date "1997-09-01" @default.
• W1988766686 modified "2023-09-30" @default.
• W1988766686 title "Electron diffraction study of the nitrogen dioxide molecular structure at 294, 480, and 691 K" @default.
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• W1988766686 doi "https://doi.org/10.1016/s0022-2860(96)09588-9" @default.
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