Matches in SemOpenAlex for { <https://semopenalex.org/work/W1988780164> ?p ?o ?g. }
- W1988780164 endingPage "1250" @default.
- W1988780164 startingPage "1242" @default.
- W1988780164 abstract "The superoxidized MnIIIMnIV state of dimanganese catalase from Thermus thermophilus and a series of structurally similar MnIIIMnIV complexes were investigated using continuous wave (CW) and pulsed EPR spectroscopy at X- (9 GHz), Q- (34 GHz), and W-band (94 GHz) frequencies. The bis(μ-oxo) or bis(μ-oxo)(μ-carboxylato) bridged complexes exhibit strong antiferromagnetic coupling (|J| > 100 cm-1). Relevant EPR parameters (G- and 55Mn hyperfine coupling tensors) are obtained by spectral simulations and yield a consistent data set for all frequency bands. Two mechanisms that lead to EPR line broadening are discussed. The advantage of our fitting strategy, i.e., precise determination of the G-tensor from high-field/frequency and hyperfine couplings from low-frequency EPR spectra, over conventional procedures is outlined. Comparison of the G- and 55Mn hyperfine tensors of the model complexes with those of dimanganese catalase show that both values are sensitive probes for small structural changes." @default.
- W1988780164 created "2016-06-24" @default.
- W1988780164 creator A5005152988 @default.
- W1988780164 creator A5024748745 @default.
- W1988780164 creator A5025327863 @default.
- W1988780164 creator A5073896912 @default.
- W1988780164 creator A5078676088 @default.
- W1988780164 creator A5083711185 @default.
- W1988780164 creator A5084861865 @default.
- W1988780164 date "2003-01-08" @default.
- W1988780164 modified "2023-10-16" @default.
- W1988780164 title "Multifrequency EPR Investigation of Dimanganese Catalase and Related Mn(III)Mn(IV) Complexes" @default.
- W1988780164 cites W1602571347 @default.
- W1988780164 cites W1964992309 @default.
- W1988780164 cites W1965507438 @default.
- W1988780164 cites W1965689680 @default.
- W1988780164 cites W1965767807 @default.
- W1988780164 cites W1966824945 @default.
- W1988780164 cites W1968146519 @default.
- W1988780164 cites W1970073097 @default.
- W1988780164 cites W1991685909 @default.
- W1988780164 cites W1991821623 @default.
- W1988780164 cites W1995414833 @default.
- W1988780164 cites W1999701932 @default.
- W1988780164 cites W2009259259 @default.
- W1988780164 cites W2015806821 @default.
- W1988780164 cites W2020382467 @default.
- W1988780164 cites W2026240821 @default.
- W1988780164 cites W2029242598 @default.
- W1988780164 cites W2043456147 @default.
- W1988780164 cites W2044783088 @default.
- W1988780164 cites W2046787608 @default.
- W1988780164 cites W2047451626 @default.
- W1988780164 cites W2050224748 @default.
- W1988780164 cites W2051384818 @default.
- W1988780164 cites W2052220085 @default.
- W1988780164 cites W2057049928 @default.
- W1988780164 cites W2058234128 @default.
- W1988780164 cites W2065277070 @default.
- W1988780164 cites W2065330180 @default.
- W1988780164 cites W2073753774 @default.
- W1988780164 cites W2085396388 @default.
- W1988780164 cites W2089655474 @default.
- W1988780164 cites W2090688963 @default.
- W1988780164 cites W2091303659 @default.
- W1988780164 cites W2092295241 @default.
- W1988780164 cites W2095140339 @default.
- W1988780164 cites W2122520645 @default.
- W1988780164 cites W2140135142 @default.
- W1988780164 cites W2142813840 @default.
- W1988780164 cites W2763512234 @default.
- W1988780164 cites W2950664137 @default.
- W1988780164 doi "https://doi.org/10.1021/jp0259768" @default.
- W1988780164 hasPublicationYear "2003" @default.
- W1988780164 type Work @default.
- W1988780164 sameAs 1988780164 @default.
- W1988780164 citedByCount "60" @default.
- W1988780164 countsByYear W19887801642012 @default.
- W1988780164 countsByYear W19887801642013 @default.
- W1988780164 countsByYear W19887801642014 @default.
- W1988780164 countsByYear W19887801642015 @default.
- W1988780164 countsByYear W19887801642016 @default.
- W1988780164 countsByYear W19887801642017 @default.
- W1988780164 countsByYear W19887801642018 @default.
- W1988780164 countsByYear W19887801642019 @default.
- W1988780164 countsByYear W19887801642023 @default.
- W1988780164 crossrefType "journal-article" @default.
- W1988780164 hasAuthorship W1988780164A5005152988 @default.
- W1988780164 hasAuthorship W1988780164A5024748745 @default.
- W1988780164 hasAuthorship W1988780164A5025327863 @default.
- W1988780164 hasAuthorship W1988780164A5073896912 @default.
- W1988780164 hasAuthorship W1988780164A5078676088 @default.
- W1988780164 hasAuthorship W1988780164A5083711185 @default.
- W1988780164 hasAuthorship W1988780164A5084861865 @default.
- W1988780164 hasConcept C104317684 @default.
- W1988780164 hasConcept C113196181 @default.
- W1988780164 hasConcept C121332964 @default.
- W1988780164 hasConcept C1276947 @default.
- W1988780164 hasConcept C131538251 @default.
- W1988780164 hasConcept C155355069 @default.
- W1988780164 hasConcept C184779094 @default.
- W1988780164 hasConcept C185592680 @default.
- W1988780164 hasConcept C187961010 @default.
- W1988780164 hasConcept C26873012 @default.
- W1988780164 hasConcept C2780883830 @default.
- W1988780164 hasConcept C32891209 @default.
- W1988780164 hasConcept C43617362 @default.
- W1988780164 hasConcept C46141821 @default.
- W1988780164 hasConcept C4839761 @default.
- W1988780164 hasConcept C547475151 @default.
- W1988780164 hasConcept C55493867 @default.
- W1988780164 hasConcept C62520636 @default.
- W1988780164 hasConcept C8010536 @default.
- W1988780164 hasConceptScore W1988780164C104317684 @default.
- W1988780164 hasConceptScore W1988780164C113196181 @default.
- W1988780164 hasConceptScore W1988780164C121332964 @default.
- W1988780164 hasConceptScore W1988780164C1276947 @default.
- W1988780164 hasConceptScore W1988780164C131538251 @default.