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• W1988793485 abstract "In this study, two different sizes of calcium carbonates (CaCO3) were blended and filled into polyamide66 (PA66). The effect of CaCO3 on the crystallization behavior of PA66 is investigated by differential scanning calorimeter (DSC). The melting measurement results indicated PA66/CaCO3 composites have secondary crystallization phenomena, which means that the crystallization process is more complicated. The crystallization temperature of the efficient size distribution samples is lower than that of the single size distribution samples. The isothermal crystallization kinetics experimental results showed that PA66/CaCO3 has the heterogeneous nucleation process, while the pure PA66 has homogeneous nucleation process. Compared with the composites filled with single-size CaCO3, both the crystallization rate constant (K) and their Avrami exponents (n) of isothermal crystallization kinetics increase. The rheological measurement result shows that the shear viscosity of the efficient size distribution composites is lower than that of the single size distribution samples. The result can be used to explain that the experimental results of crystal morphology and crystallization. The lower viscosity of the system is, the harder nucleation, the easier crystal formation." @default.
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• W1988793485 date "2012-04-01" @default.
• W1988793485 modified "2023-10-01" @default.
• W1988793485 title "Studies on Crystal Morphology and Crystallization Kinetics of Polyamide 66 Filled with CaCO₃of Different Sizes and Size Distribution" @default.
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• W1988793485 doi "https://doi.org/10.1080/03602559.2012.659308" @default.
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