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- W1988820630 abstract "Presents and discusses the high-resolution optical spectrum associated with 5I8(A1) implies 5F5(E), 5I8(A2) implies 5F5(E) transitions of a tetragonal Ho3+ centre in CaF2. The lowest crystal-field levels in the ground multiplet are two singlets separated by approximately 1.7 cm-1. With the closeness of the states, the hyperfine interaction gives rise to strongly mixed wavefunctions and anomalously large pseudoquadrupole splittings. The mixing also results in an enhanced magnetic moment associated with the hyperfine components of the singlets and the magnitude is found to depend on the hyperfine level. Consequently, there are separate superhyperfine resonances associated with each of the four non-degenerate hyperfine levels and these resonances were observed by ODNMR techniques when holeburning in the various optical hyperfine lines. More than 30 superhyperfine resonances were detected and they are assigned to interstitial and groups of near-neighbour F- ions." @default.
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- W1988820630 date "1993-03-01" @default.
- W1988820630 modified "2023-10-14" @default.
- W1988820630 title "Hyperfine coupling between crystal-field levels in the tetragonal centre of CaF2:Ho3+" @default.
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- W1988820630 doi "https://doi.org/10.1088/0953-8984/5/9/018" @default.
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