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- W1988822495 abstract "Abstract The synthesis and characterization of the [M(dmit)(phen)] complexes [M = Pd(II), Pt(II); H2dmit = 4,5-dimercapto-1,3-dithiole-2-thione; phen = 1,10-phenanthroline) and of the iodinated [M(dmit)(phen)]I compounds are described. The conductivity of [M(admit)(phen)] increases upon oxidation by a factor of 106, and is ca. 5 × 10−3 ohm− cm− for the [M(admit)(phen)]I compounds. The nature of the iodine species in these solids is determined by UV-visible and resonance Raman spectroscopies. The only polyiodide present is I−3 and, thus, the charge distribution can be expressed as [M(dmit) (phen)0.33+[I−3]0.33." @default.
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- W1988822495 date "1986-01-01" @default.
- W1988822495 modified "2023-09-25" @default.
- W1988822495 title "Synthesis and resonance raman study of conductive iodinated materials derived from [M(dmit)(phen)] complexes [M = Pd(II), Pt(II)]" @default.
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- W1988822495 doi "https://doi.org/10.1016/s0277-5387(00)87134-x" @default.
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