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- W1988824892 abstract "Tracer diffusion coefficients of LaIII, DLa, were measured in HCl (1·0M–10·0M) and HClO4(1·1M–9·76M). DLa in HCl decreased slowly as the HCl concentration increased; at 10M-HCl DLa is still ca. 65% of D°La(0·62 × 10–5 cm2 s–1). In HClO4, DLa remains nearly constant at 0·6 × 10–5 cm2 s–1 from 1·1M to ca. 3·5M-acid and then decreases rapidly to 0·2 × 10–5 cm2 s–1 in 9·76M-acid.For the highest concentrations of acid (ca. 10M) studied, DLa in HClO4 is about half the value in HCl. However, the product of the relative diffusion coefficient and the relative viscosity has the same value in both systems when the activities of water are equal." @default.
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- W1988824892 date "1971-01-01" @default.
- W1988824892 modified "2023-10-16" @default.
- W1988824892 title "Diffusion studies. Part III. Tracer diffusion coefficients of lanthanum(III) in concentrated solutions of HCl and HClO4at 25 °C" @default.
- W1988824892 doi "https://doi.org/10.1039/j19710003556" @default.
- W1988824892 hasPublicationYear "1971" @default.
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