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• W1988843430 endingPage "13218" @default.
• W1988843430 startingPage "13208" @default.
• W1988843430 abstract "A novel ruthenium sensitizer ((TBA)[Ru(3',4'-dicarboxyterpyridine)(NCS)3], TBA = tetrabutylammonium, TUS-28) has been synthesized as an improved model sensitizer for (TBA)[Ru(4'-(3,4-dicarboxyphenyl)terpyridine)(NCS)3] (TUS-20). The molar absorptivity of TUS-28 in the whole visible region was smaller than that of TUS-20 due to the absence of the phenyl ring at the terpyridine ligand. On the other hand, the energy levels of HOMO and LUMO of TUS-28 were still suitable for effective electron transfer reactions in dye-sensitized solar cells (DSCs). TUS-28 did not show a superior adsorptivity to the TiO2 surface just like TUS-20, even though TUS-28 has an ortho-dicarboxyl group which is reported to be an efficient anchoring unit. ATR-IR measurements revealed that both carboxyl groups of TUS-28 participate in binding to the TiO2 surface just like TUS-20. Therefore, steric hindrance between the hydrogen atom at the 4-position of 3',4'-dicarboxyterpyridine and the OH group at the TiO2 surface seems to retard the rapid adsorption, and to weaken the binding strength of TUS-28. The DSC with TUS-28 showed 8.2% conversion efficiency, which is higher than that of TUS-20 (7.5%). The J(sc) value of the DSC with TUS-28 was larger than that of TUS-20 even though the amount of dye adsorption of TUS-28 was smaller than that of TUS-20. A more effective electron injection reaction is considered to contribute mainly to the efficiency improvement of TUS-28 since the path length of the electron injection from TUS-28 to the conduction band of the TiO2 is shorter than that of TUS-20 due to the absence of the phenyl ring." @default.
• W1988843430 created "2016-06-24" @default.
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• W1988843430 date "2014-01-01" @default.
• W1988843430 modified "2023-10-16" @default.
• W1988843430 title "Ruthenium sensitizers having an ortho-dicarboxyl group as an anchoring unit for dye-sensitized solar cells: synthesis, photo- and electrochemical properties, and adsorption behavior to the TiO₂ surface" @default.
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• W1988843430 doi "https://doi.org/10.1039/c4dt01450b" @default.
• W1988843430 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25048989" @default.
• W1988843430 hasPublicationYear "2014" @default.
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