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- W1988846364 abstract "Cunninghamella elegans oxidizes benzo[a]pyrene to several metabolites that are soluble in ethyl acetate. One of these, trans-7,8-dihydroxyl-7,8-dihydrobenzo[a]pyrene, was converted to a di-(−)menthoxyacetate that had the same retention time on high pressure liquid chromatography as the di-(−)menthoxyacetate formed from (−)-trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene. Radioactive trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene formed by C. elegans was mixed with synthetic racemic dihydrodiol prior to reaction with (−)menthoxyacetyl chloride. Resolution of the resulting diastereomers by high pressure liquid chromatography showed that more than ninety-five percent of the radioactivity cochromatographed with the di-(−)menthoxyacetate formed from (−)-trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene. These results are similar to those reported for mammals which form the more tumorigenic (−)-enantiomer of trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene." @default.
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- W1988846364 date "1980-05-01" @default.
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- W1988846364 title "Fungal oxidation of benzo[a]pyrene: Formation of (−)-trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene by Cunninghamella elegans" @default.
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- W1988846364 doi "https://doi.org/10.1016/s0006-291x(80)80210-5" @default.
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