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• W1988856283 abstract "Abstract The quantum yield for photoaquation of trans -[Ru(bipy) 2 Cl 2 ] + , where bipy2,2′-bipyridine, is found to be 1.5 × 10 −2 mol Einstein −1 , when irradiated at its ligand field band. The estimated activation enthalpy for the thermoaquation of this complex is 20 kcal mol −1 . In comparison with trans -[Ru(en) 2 Cl 2 ] + , where enethylenediamine, the bipy complex has a higher quantum efficiency than the en complex. The difference between the reactivities in the ground state and excited state can be understood within the framework of the ligand field model. The electronic interaction between Ru(III) and ligands that stabilizes the ground state also stabilizes the intermediate in the photoaquation reaction. Hence the bipy complex is found to be less reactive toward aquation in the ground state than the en complex is but to be more reactive in the excited state." @default.
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• W1988856283 date "1994-05-01" @default.
• W1988856283 modified "2023-09-27" @default.
• W1988856283 title "Photoaquation and aquation of trans-dichlorobis (bipyridine)ruthenium(III)" @default.
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• W1988856283 doi "https://doi.org/10.1016/1010-6030(93)03759-a" @default.
• W1988856283 hasPublicationYear "1994" @default.
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