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• W1988876698 abstract "For the first time the structure of the polycristalline α - Bi4V2O11 low-temperature form has been determined by Rietveld analysis using X-ray and neutron diffraction data in the C2/m space group. Although this phase was phase was previously claimed to be orthorhombic, it is actually monoclinic as we deduced from XRPD patterns. The true cell arises from a six-fold commensurate modulation of the orthorhombic mean cell along the cM monoclinic axis, but because of the weakness of the intensity of some diffraction lines due to the six-fold superstructure, only the three-fold could be investigated. α - Bi4V2O11 is structurally related to the parent Aurivillius prototype. However the perovskite layers with composition (VO3.5□0.5)2− with interleave the (Bi2O2)2+ slabs are broken into files made up of alternating vanadium - oxygen tetrahedra and oxygen-deficient octahedra, running along the modulation cM axis. The one-dimensional modulation depends on oxygen long-range ordering and can be viewed as resulting from coupled valence modulations of both vanadium and bismuth cations." @default.
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• W1988876698 date "1994-02-01" @default.
• W1988876698 modified "2023-10-01" @default.
• W1988876698 title "Crystal structure of low-temperature form of bismuth vanadium oxide determined by rietveld refinement of X-ray and neutron diffraction data (α - Bi4V2O11)" @default.
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• W1988876698 doi "https://doi.org/10.1016/0025-5408(94)90138-4" @default.
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