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- W1988923193 abstract "Extensive catalytic waves of Co(II) are observed in N3−/HN3 buffers, in which hydrogen discharge is not the dominant process, but rather HN3 reduction to NH4+ and N2. Cobalt(I) was shown to be the active intermediate of the catalytic process. The rate-determing step was found to be the Co(I) reduction to the metal. Heterogeneous rate constants were calculated and relationships with average ligand number were derived." @default.
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- W1988923193 date "1981-08-01" @default.
- W1988923193 modified "2023-10-18" @default.
- W1988923193 title "Catalytic polarographic wave of cobalt(II) in sodium azide with hydrazoic acid" @default.
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- W1988923193 doi "https://doi.org/10.1016/s0022-0728(81)80328-2" @default.
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