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- W1988968322 abstract "The methylenecyclopropanes 1, 2, 11 upon reaction with α-donorsubstituted acrylonitriles 3a, 3c gave two types of products, regular [2+2] cycloadducts 6, 8, 10, 13, 14 and thiacyclopentane derivatives 7, 9. The capto-dative substituted methylenecyclopropane 12 preferentially homodimerized to 15 even in the presence of 2. The capto-dative olefin 3a also added across the central single bonds of a bicyclo[1.1.0.]butane derivative 4b and bicyclo[2.1.0]pentane 5a to yield 16 and 19 via diradical intermediates." @default.
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- W1988968322 date "1986-01-01" @default.
- W1988968322 modified "2023-10-10" @default.
- W1988968322 title "Cycloadditions of methylenecyclopropanes and strained bicyclo[n.1.0]alkanes to radicophilic olefins" @default.
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- W1988968322 doi "https://doi.org/10.1016/s0040-4020(01)87348-8" @default.
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