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- W1988996896 abstract "An orthogonally protected derivative 1 of (2R,3R,4S)-4,7-diamino-2,3-dihydroxyheptanoic acid, the unusual amino acid residue of the biologically active marine peptides such as callipeltins A and D and neamphamide A, was efficiently prepared in 10 steps and 30% overall yield from a commercially available l-ornithine derivative 2. The key step includes the N-diphenylmethylene-controlled diastereoselective dihydroxylation of (Z)-ester 3 with >13:1 selectivity for the desired isomer." @default.
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- W1988996896 date "2006-03-16" @default.
- W1988996896 modified "2023-10-10" @default.
- W1988996896 title "Stereoselective Synthesis of Protected (2<i>R</i>,3<i>R</i>,4<i>S</i>)-4,7-Diamino-2,3-dihydroxyheptanoic Acid: A Novel Amino Acid of Callipeltins A and D" @default.
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- W1988996896 doi "https://doi.org/10.1021/jo052676o" @default.
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