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- W1989014030 abstract "The pressure composition isotherm of the Er6Fe23-H2 system studied at 0°C reveals the presence of three different hydride phases. Maximum absorption is typically 14 hydrogen atoms/formula unit in Er6Fe23 and Ho6Fe23 compared to about 22 in the isostructural Mn compounds. During hydrogenation Ho6Fe23 remains cubic with lattice parameter which increases from 12.034 Å to 12.399 Å. Upon hydrogenation Er6Fe23 exhibits the very surprising behavior of transforming from a cubic (a = 12.004 Å) to a tetragonal structure (a = 12.131 Å, c = 12.601 Å). In spite of their contrasting crystallographic features both hydrides exhibit similar magnetic behavior, relative to the parent compounds, namely, lowering of both the saturation moment at 4.2 and the compensation temperature and an increase in the saturation moment at room temperature. The results of magnetic measurements may be understood by assuming an increase in the iron moment in these compounds on hydrogen absorption." @default.
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- W1989014030 date "1981-10-01" @default.
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- W1989014030 title "Influence of hydrogen on structure and magnetic properties of Ho6Fe23 and Er6Fe23" @default.
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- W1989014030 doi "https://doi.org/10.1016/0038-1098(81)90149-6" @default.
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