Matches in SemOpenAlex for { <https://semopenalex.org/work/W1989025177> ?p ?o ?g. }
- W1989025177 endingPage "7752" @default.
- W1989025177 startingPage "7735" @default.
- W1989025177 abstract "Abstract. Atmospheric particulate matter (PM) was fractionated in six aerodynamic sizes, > 7.2, 7.2–3, 3–1.5, 1.5–1, 1–0.5 and < 0.5 μm, using a cascade impactor. These fractions were collected at urban and rural sites during warm and cold seasons. Organic tracer compounds, such as levoglucosan, isoprene, pinene oxidation products, polycyclic aromatic hydrocarbons and quinones, were analyzed by gas chromatography coupled with mass spectrometry. These analyses showed that the composition in the smallest size fractions (< 0.5 μm) was more uniform than in the larger sizes (7.2> PM > 0.5 μm). Thus, markers of photochemically synthesized organic compounds or combustion sources, either biomass burning or traffic emissions, were predominantly observed in the fraction < 0.5 μm, whereas the larger particles were composed of mixed sources from combustion processes, vegetation emissions, soil resuspension, road dust, urban lifestyle activities and photochemically synthesized organic compounds. Important seasonal differences were observed at the rural site. In the < 0.5 μm fraction these were related to a strong predominance of biomass burning in the cold period and photochemically transformed biogenic organic compounds in the warm period. In the 7.2 > PM > 0.5 μm fractions the differences involved predominantly soil-sourced compounds in the warm period and mixed combustion sources, photochemical products and vegetation emissions in the cold. Multivariate curve resolution/alternating least squares showed that these organic aerosols essentially originated from six source components. Four of them reflected primary emissions related to either natural products, e.g., vegetation emissions and upwhirled soil dust, or anthropogenic contributions, e.g., combustion products and compounds related to urban lifestyle activities like vehicular exhaust and tobacco smoking. Two secondary organic aerosol components were identified. They accumulated in the smallest (< 0.5 μm) or in the larger fractions (> 0.5 μm) and involved strong or mild photochemical transformations of vegetation precursor molecules, respectively. Toxicologically relevant information was also disclosed with the present approach. Thus, the strong predominance of biomass burning residues at the rural site during the cold period involved atmospheric concentrations of polycyclic aromatic hydrocarbons that were 3 times higher than at the urban sites and benzo[a]pyrene concentrations above legal recommendations." @default.
- W1989025177 created "2016-06-24" @default.
- W1989025177 creator A5060323529 @default.
- W1989025177 creator A5089086652 @default.
- W1989025177 date "2015-07-15" @default.
- W1989025177 modified "2023-10-03" @default.
- W1989025177 title "Particle size-resolved source apportionment of primary and secondary organic tracer compounds at urban and rural locations in Spain" @default.
- W1989025177 cites W1634791384 @default.
- W1989025177 cites W1963674693 @default.
- W1989025177 cites W1964400493 @default.
- W1989025177 cites W1964773166 @default.
- W1989025177 cites W1966779205 @default.
- W1989025177 cites W1974047321 @default.
- W1989025177 cites W1974682357 @default.
- W1989025177 cites W1974703729 @default.
- W1989025177 cites W1974728353 @default.
- W1989025177 cites W1975262842 @default.
- W1989025177 cites W1975706867 @default.
- W1989025177 cites W1978457685 @default.
- W1989025177 cites W1981752903 @default.
- W1989025177 cites W1982969719 @default.
- W1989025177 cites W1984858137 @default.
- W1989025177 cites W1984949361 @default.
- W1989025177 cites W1988063372 @default.
- W1989025177 cites W1989889548 @default.
- W1989025177 cites W1991571385 @default.
- W1989025177 cites W1993994463 @default.
- W1989025177 cites W2002761793 @default.
- W1989025177 cites W2003514756 @default.
- W1989025177 cites W2004271819 @default.
- W1989025177 cites W2004636844 @default.
- W1989025177 cites W2005829248 @default.
- W1989025177 cites W2005959500 @default.
- W1989025177 cites W2012921378 @default.
- W1989025177 cites W2013192597 @default.
- W1989025177 cites W2015093096 @default.
- W1989025177 cites W2016935109 @default.
- W1989025177 cites W2017105793 @default.
- W1989025177 cites W2019566939 @default.
- W1989025177 cites W2032415871 @default.
- W1989025177 cites W2035527619 @default.
- W1989025177 cites W2039464913 @default.
- W1989025177 cites W2040985765 @default.
- W1989025177 cites W2041585507 @default.
- W1989025177 cites W2042266353 @default.
- W1989025177 cites W2042308548 @default.
- W1989025177 cites W2044494983 @default.
- W1989025177 cites W2044536404 @default.
- W1989025177 cites W2046804437 @default.
- W1989025177 cites W2048053880 @default.
- W1989025177 cites W2048943000 @default.
- W1989025177 cites W2052701607 @default.
- W1989025177 cites W2053071262 @default.
- W1989025177 cites W2053745186 @default.
- W1989025177 cites W2055181986 @default.
- W1989025177 cites W2062609292 @default.
- W1989025177 cites W2063261611 @default.
- W1989025177 cites W2063514672 @default.
- W1989025177 cites W2067209936 @default.
- W1989025177 cites W2068210284 @default.
- W1989025177 cites W2068968500 @default.
- W1989025177 cites W2069737285 @default.
- W1989025177 cites W2069753895 @default.
- W1989025177 cites W2070018987 @default.
- W1989025177 cites W2073446008 @default.
- W1989025177 cites W2075275228 @default.
- W1989025177 cites W2075668796 @default.
- W1989025177 cites W2076335579 @default.
- W1989025177 cites W2081437286 @default.
- W1989025177 cites W2092280582 @default.
- W1989025177 cites W2092691550 @default.
- W1989025177 cites W2092730081 @default.
- W1989025177 cites W2098655029 @default.
- W1989025177 cites W2104786214 @default.
- W1989025177 cites W2105203677 @default.
- W1989025177 cites W2106528128 @default.
- W1989025177 cites W2110878334 @default.
- W1989025177 cites W2112052552 @default.
- W1989025177 cites W2113837391 @default.
- W1989025177 cites W2114191971 @default.
- W1989025177 cites W2116507044 @default.
- W1989025177 cites W2117335074 @default.
- W1989025177 cites W2118719107 @default.
- W1989025177 cites W2122574093 @default.
- W1989025177 cites W2127510753 @default.
- W1989025177 cites W2129432128 @default.
- W1989025177 cites W2131885330 @default.
- W1989025177 cites W2135822043 @default.
- W1989025177 cites W2143525187 @default.
- W1989025177 cites W2144923407 @default.
- W1989025177 cites W2145651246 @default.
- W1989025177 cites W2153765402 @default.
- W1989025177 cites W2158645536 @default.
- W1989025177 cites W2160220764 @default.
- W1989025177 cites W2161175616 @default.
- W1989025177 cites W2163854746 @default.
- W1989025177 cites W2166147132 @default.
- W1989025177 cites W2166604768 @default.