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• W1989080216 abstract "We present a study on the electronic structure of V and V3Pt, based on photoemission (XPS and UPS) measurements and on the examination of previous band calculations, specific heat, susceptibility and NMR results. Photoemission spectra on pure V, in particular the XPS one, show a good agreement with band calculations ; the HeII spectrum exhibits a strong satellite which could be attributed to a simple Auger effect or to a resonant process. Photoemission on V3Pt allows an evaluation of the partial densities of states (PDOS) ; the Vanadium PDOS is similar to that of pure element, at least for the upper part of the valence band ; meanwhile the Platinium partial EDOS is drastically modified. This can be understood in the framework of electronic structure of compounds involving early and late transition metals where the atomic structure seems to play an important role. An evaluation of the EDOS's at the Fermi level n(EF) can also be tempted and compared to those obtained from the other mentioned techniques. Therefore it is suggested that for Vanadium n(EF) is similar to that of pure element ; for Platinium n(EF) is strongly reduced. Finally the analysis of the electronic specific heat of V, Pt and V3Pt indicates that the parameter of electron-phonon coupling determined by the Mc Millan's theory is likely underesti:ated, due to the occurence of an estimated coupling in V and V3Pt." @default.
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• W1989080216 date "1982-08-01" @default.
• W1989080216 modified "2023-09-26" @default.
• W1989080216 title "Photoemission, NMR, susceptibility and specific heat in V and A15 V3Pt" @default.
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• W1989080216 doi "https://doi.org/10.1016/0038-1098(82)91162-0" @default.
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