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- W1989088918 abstract "Vacuum ultraviolet absorption spectroscopy and fluorescence analysis under selective optical excitation have been combined to deduce the electronic structure of Cl2. Between 73000 and 81000 cm−1 five bound electronic states could be analysed. Some of them are affected by pronounced Rydberg—valence mixing. Especially the 1 1∑u+ state clearly yields a double-well structure which results from an avoided crossing between an ionic valence and a Rydberg state. The double-well structure is responsible for an irregular vibrational sequence between 73000 and 74500 cm−1 which either prevented an analysis in earlier investigations or lead to wrong assignments. The FC factors of the 1 1∑u+ fluorescence with its bound—bound and bound—free contributions between ≈ 73000 and 50000 cm−1 are also severely affected by the double-well structure. The results are compared with the first ab initio calculations of the electronic structure of Cl2. In general, excellent agreement is found." @default.
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- W1989088918 date "1983-04-01" @default.
- W1989088918 modified "2023-10-06" @default.
- W1989088918 title "Spectroscopic investigation of the electronic structure of the chlorine molecule in the VUV" @default.
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- W1989088918 doi "https://doi.org/10.1016/0301-0104(83)85043-5" @default.
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