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- W1989115717 abstract "Acrylic hydrogels based on 2-hydroxyethyl methacrylate, H, have been synthesized by copolymerization reaction of this monomer with 2-ethylhexyl acrylate, E, using AIBN as initiator. Reactivity ratios were estimated from copolymerization reactions carried out in solution and at low conversion, by using both linearization and nonlinearization methods. They were found to be rE = 0.29 and rH = 2.54. The swelling behavior of the hydrogels was studied by immersion of copolymer films prepared by bulk copolymerization, in water at different temperatures. Equilibrium water uptake was strongly dependent on composition and decreased with the E content in the copolymer. Fickian behavior was observed in all cases for reduced sorption coefficients lower than 0.4. The diffusion coefficient was found to decrease with increasing E content in the copolymer. A value of apparent activation energy for the diffusion process of 8.8 kJ/mol was obtained for poly(2-hydroxyethyl methacrylate); however, H/E copolymers did not obey t..." @default.
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- W1989115717 date "1997-12-01" @default.
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- W1989115717 title "Polymeric Hydrophilic Hydrogels with Flexible Hydrophobic Chains. Control of the Hydration and Interactions with Water Molecules" @default.
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- W1989115717 doi "https://doi.org/10.1021/ma970863l" @default.
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