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- W1989146280 abstract "The radiation-induced polymerization of styrene in both liquid and solid states has been investigated at high pressure in the temperature range 20–50°C. In the liquid phase pressure increases the polymerization rate as well as the molecular weight of the polymer in agreement with the results for chemically-initiated polymerization. In particular, activation volume and energy are consistent with literature values. When the monomer has undergone the liquid-solid transition a sudden increase in the polymerization rate takes place. However the latter falls again to negligible values for a comparatively small pressure excess above the solidification point. The mechanism of the solid-state polymerization in the high-rate region is considered in the light of existing theories." @default.
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- W1989146280 date "1970-11-01" @default.
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- W1989146280 title "Polymerization induced by gamma radiation of styrene under pressure" @default.
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- W1989146280 doi "https://doi.org/10.1016/0032-3861(70)90089-3" @default.
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