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- W1989152316 abstract "Partially esterified alkylenediphosphonic acids were shown to be effective solvent extraction reagents for the removal of actinide cations from acidic aqueous solutions into conventional organic solvents. As a first step in an effort to design diphosphonic acid extractants that are soluble in supercritical carbon dioxide, we prepared and characterized a novel series of silyl-substituted alkylenediphosphonic acids. The aggregation of these extractants in toluene at 25°C was studied by vapor pressure osmometry. Their solvent extraction chemistry was investigated by employing radiotracers to determine the distribution ratios for selected metal ions between an acidic aqueous phase and an organic phase containing the diphosphonic acid extractant. To determine the effect of incorporating a silicon functionality into diphosphonic acids, the aggregation and solvent extraction properties of the silyl-substituted alkylenediphosphonic acids were compared with those of the conventional alkyl-substituted di(2-ethylhex..." @default.
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- W1989152316 date "2003-01-08" @default.
- W1989152316 modified "2023-09-23" @default.
- W1989152316 title "Aggregation, Metal Ion Extraction, and Solubility Properties of Silyl-Substituted Alkylenediphosphonic Acids" @default.
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- W1989152316 doi "https://doi.org/10.1081/ss-120022570" @default.
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