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- W1989202281 abstract "In order to study the mechanism and parameters of hydrogen diffusion in the hexagonal (C14-type) Laves-phase $mathrm{Zr}{mathrm{Mn}}_{2}$, we have performed quasielastic neutron scattering measurements for $mathrm{Zr}{mathrm{Mn}}_{2}{mathrm{H}}_{3}$ over the temperature range $10--390phantom{rule{0.3em}{0ex}}mathrm{K}$. It is found that the diffusive motion of hydrogen in this system can be described in terms of at least two jump processes: a fast localized H motion with the jump rate ${ensuremath{tau}}_{l}^{ensuremath{-}1}$ and a slower process with the rate ${ensuremath{tau}}_{d}^{ensuremath{-}1}$ associated with H jumps leading to long-range diffusion. The temperature dependence of ${ensuremath{tau}}_{d}^{ensuremath{-}1}$ in the range $225--390phantom{rule{0.3em}{0ex}}mathrm{K}$ follows the Arrhenius law with the activation energy of $124ifmmodepmelsetextpmfi{}4phantom{rule{0.3em}{0ex}}mathrm{meV}$. In the same range, the temperature dependence of ${ensuremath{tau}}_{l}^{ensuremath{-}1}$ deviates from the Arrhenius behavior and is considerably weaker than that of ${ensuremath{tau}}_{d}^{ensuremath{-}1}$. The $Q$ dependence of the elastic incoherent structure factor (studied up to ${Q}_{mathrm{max}}ensuremath{approx}3.8phantom{rule{0.3em}{0ex}}{mathrm{AA{}}}^{ensuremath{-}1}$) suggests that the fast localized H motion in $mathrm{Zr}{mathrm{Mn}}_{2}{mathrm{H}}_{3}$ corresponds to two-site jumps within pairs of closely spaced interstitial ${mathrm{Zr}}_{2}{mathrm{Mn}}_{2}$ sites." @default.
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- W1989202281 date "2007-09-17" @default.
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- W1989202281 title "Hydrogen jump diffusion in C14-type<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mi mathvariant=normal>Zr</mml:mi><mml:msub><mml:mi mathvariant=normal>Mn</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mi mathvariant=normal>H</mml:mi><mml:mn>3</mml:mn></mml:msub></mml:mrow></mml:math>: Quasielastic neutron scattering study" @default.
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- W1989202281 doi "https://doi.org/10.1103/physrevb.76.104305" @default.
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