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- W1989202327 abstract "A one‐step synthesis of a new sulfur‐containing compound, L‐α‐amino‐β‐thio‐ϵ‐caprolactam from L‐cysteine methyl ester and 2‐chloroethylamine has been described. This intramolecular cyclic amide of S ‐(β‐aminoethyl)‐L‐cysteine serves as a good substrate for α‐amino‐ϵ‐caprolactam racemase. L‐α‐Amino‐β‐thio‐ϵ‐caprolactam is racemized more than 3 times faster and binds about 4‐fold stronger to the enzyme than L‐α‐amino‐ϵ‐caprolactam itself. Optimum pH for racemization of this new compound is about 10.0." @default.
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- W1989202327 date "1984-08-20" @default.
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- W1989202327 title "L-α-Amino-β-thio-ϵ-caprolactam, a new sulfur-containing Substrate for α-amino-ϵ-caprolactam racemase" @default.
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- W1989202327 doi "https://doi.org/10.1016/0014-5793(84)81081-9" @default.
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