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• W1989227790 endingPage "1428" @default.
• W1989227790 startingPage "1421" @default.
• W1989227790 abstract "The hydrothermal reaction of Na2MoO4, Ag(CH3CO2), tetra-2-pyridylpyrazine (tpyprz), HF and water at 170 °C for 48 h yields [{Ag4(tpyprz)2(H2O)}Mo8O26] (1) as colorless plates. The structure of 1 is a two-dimensional network, constructed from {Ag4(tpyprz)2(H2O)}4n+n chains linked through ζ-Mo8O264− clusters. The chains exhibit three distinct Ag(I) environments: a four coordinate {AgN4} site, a three coordinate {AgN2Oaqua} site, and four coordinate {AgN3Ooxo} site which links to the molybdate cluster. Each cluster is connected by bridging oxo-groups to two silver/tpyprz chains to form the network architecture. Crystal data: C24H17Ag2Mo4N6O13.5, fw 1204.94, orthorhombic Pccn, a=20.8234(9)Å, b=14.5076(6)Å, c=20.3537(9)Å, V=6148.9(5)Å3, Z=8, Dcalc=2.603g cm−3." @default.
• W1989227790 created "2016-06-24" @default.
• W1989227790 creator A5076995372 @default.
• W1989227790 creator A5080355402 @default.
• W1989227790 date "2004-12-01" @default.
• W1989227790 modified "2023-09-24" @default.
• W1989227790 title "A two-dimensional bimetallic oxide constructed from ζ-octamolybdate clusters and Ag(I)-tpyprz cationic polymer components (tpyprz = tetra-2-pyridylpyrazine)" @default.
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• W1989227790 doi "https://doi.org/10.1016/j.solidstatesciences.2004.07.016" @default.
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