Matches in SemOpenAlex for { <https://semopenalex.org/work/W1989234039> ?p ?o ?g. }
- W1989234039 endingPage "6831" @default.
- W1989234039 startingPage "6831" @default.
- W1989234039 abstract "A novel Cu–Fe bimetal supported catalytic system was prepared and applied to the direct dimethyl carbonate (DMC) formation from methanol and CO2. The prepared catalysts were characterized by means of temperature-programmed reduction (TPR), X-ray powder diffraction (XRD), laser Raman spectra (LRS), X-ray photoelectron spectroscopy (XPS) and temperature programmed desorption (TPD). Metallic Cu, Fe and oxygen deficient Fe2O3−x (0 < x < 3) were formed during the reduction and activation step. The supported Cu–Fe bimetal catalysts exhibited good catalytic activity and high stability for the direct DMC formation. Under the reaction conditions at 120 °C and 1.2 MPa with space velocity of 360 h−1, the highest methanol conversion of 5.37% with DMC selectivity of 85.9% could be achieved. The high catalytic performance of the Cu–Fe bimetal catalysts in the DMC formation could be attributed to the interaction of base sites functioned by metallic Cu and Fe with acid sites provided by oxygen deficient Fe2O3−x (0 < x < 3) in the activation of methanol and CO2. The moderate concentration balance of acid and base sites was in favor of DMC formation." @default.
- W1989234039 created "2016-06-24" @default.
- W1989234039 creator A5021240812 @default.
- W1989234039 creator A5023429764 @default.
- W1989234039 creator A5059375094 @default.
- W1989234039 creator A5060162976 @default.
- W1989234039 creator A5066554626 @default.
- W1989234039 creator A5085506465 @default.
- W1989234039 date "2012-01-01" @default.
- W1989234039 modified "2023-10-16" @default.
- W1989234039 title "Novel Cu–Fe bimetal catalyst for the formation of dimethyl carbonate from carbon dioxide and methanol" @default.
- W1989234039 cites W117446292 @default.
- W1989234039 cites W1479706867 @default.
- W1989234039 cites W1969432371 @default.
- W1989234039 cites W1970038345 @default.
- W1989234039 cites W1973544315 @default.
- W1989234039 cites W1977495148 @default.
- W1989234039 cites W2002475785 @default.
- W1989234039 cites W2006134267 @default.
- W1989234039 cites W2012712739 @default.
- W1989234039 cites W2015542129 @default.
- W1989234039 cites W2019716301 @default.
- W1989234039 cites W2021057615 @default.
- W1989234039 cites W2025169638 @default.
- W1989234039 cites W2032797382 @default.
- W1989234039 cites W2033564504 @default.
- W1989234039 cites W2043982952 @default.
- W1989234039 cites W2045876125 @default.
- W1989234039 cites W2050195199 @default.
- W1989234039 cites W2061667389 @default.
- W1989234039 cites W2063271566 @default.
- W1989234039 cites W2063451141 @default.
- W1989234039 cites W2063515836 @default.
- W1989234039 cites W2067323007 @default.
- W1989234039 cites W2068602449 @default.
- W1989234039 cites W2078353661 @default.
- W1989234039 cites W2083459676 @default.
- W1989234039 cites W2098038251 @default.
- W1989234039 cites W2138683505 @default.
- W1989234039 cites W2146970282 @default.
- W1989234039 cites W2151330452 @default.
- W1989234039 cites W2158214258 @default.
- W1989234039 cites W2171836549 @default.
- W1989234039 cites W300993578 @default.
- W1989234039 cites W311202516 @default.
- W1989234039 cites W4238517065 @default.
- W1989234039 doi "https://doi.org/10.1039/c2ra20359f" @default.
- W1989234039 hasPublicationYear "2012" @default.
- W1989234039 type Work @default.
- W1989234039 sameAs 1989234039 @default.
- W1989234039 citedByCount "52" @default.
- W1989234039 countsByYear W19892340392013 @default.
- W1989234039 countsByYear W19892340392014 @default.
- W1989234039 countsByYear W19892340392015 @default.
- W1989234039 countsByYear W19892340392016 @default.
- W1989234039 countsByYear W19892340392017 @default.
- W1989234039 countsByYear W19892340392018 @default.
- W1989234039 countsByYear W19892340392019 @default.
- W1989234039 countsByYear W19892340392020 @default.
- W1989234039 countsByYear W19892340392021 @default.
- W1989234039 countsByYear W19892340392022 @default.
- W1989234039 countsByYear W19892340392023 @default.
- W1989234039 crossrefType "journal-article" @default.
- W1989234039 hasAuthorship W1989234039A5021240812 @default.
- W1989234039 hasAuthorship W1989234039A5023429764 @default.
- W1989234039 hasAuthorship W1989234039A5059375094 @default.
- W1989234039 hasAuthorship W1989234039A5060162976 @default.
- W1989234039 hasAuthorship W1989234039A5066554626 @default.
- W1989234039 hasAuthorship W1989234039A5085506465 @default.
- W1989234039 hasConcept C120665830 @default.
- W1989234039 hasConcept C121332964 @default.
- W1989234039 hasConcept C127413603 @default.
- W1989234039 hasConcept C13965031 @default.
- W1989234039 hasConcept C147789679 @default.
- W1989234039 hasConcept C161790260 @default.
- W1989234039 hasConcept C175708663 @default.
- W1989234039 hasConcept C178790620 @default.
- W1989234039 hasConcept C179104552 @default.
- W1989234039 hasConcept C185592680 @default.
- W1989234039 hasConcept C2778197717 @default.
- W1989234039 hasConcept C2779607525 @default.
- W1989234039 hasConcept C40003534 @default.
- W1989234039 hasConcept C42360764 @default.
- W1989234039 hasConcept C544153396 @default.
- W1989234039 hasConcept C74793105 @default.
- W1989234039 hasConceptScore W1989234039C120665830 @default.
- W1989234039 hasConceptScore W1989234039C121332964 @default.
- W1989234039 hasConceptScore W1989234039C127413603 @default.
- W1989234039 hasConceptScore W1989234039C13965031 @default.
- W1989234039 hasConceptScore W1989234039C147789679 @default.
- W1989234039 hasConceptScore W1989234039C161790260 @default.
- W1989234039 hasConceptScore W1989234039C175708663 @default.
- W1989234039 hasConceptScore W1989234039C178790620 @default.
- W1989234039 hasConceptScore W1989234039C179104552 @default.
- W1989234039 hasConceptScore W1989234039C185592680 @default.
- W1989234039 hasConceptScore W1989234039C2778197717 @default.
- W1989234039 hasConceptScore W1989234039C2779607525 @default.
- W1989234039 hasConceptScore W1989234039C40003534 @default.