Matches in SemOpenAlex for { <https://semopenalex.org/work/W1989252313> ?p ?o ?g. }
- W1989252313 endingPage "5021" @default.
- W1989252313 startingPage "5021" @default.
- W1989252313 abstract "Neutral lanthanide thioantimonate complexes with the formula [Ln(dien)2(μ-η1, η2-SbS4)]n (Ln1) (Ln = Pr 1a, Nd 1b, Sm 1c) and [Ln(dien)2(η2-SbS4)] (Ln2) (Ln = Eu 2a, Dy 2b) have been synthesized by the solvothermal reaction of antimony and sulfur powders with the corresponding lanthanide oxide in diethylenetriamine (dien). In 1a–1c, the tetrathioantimonate SbS43− anion acts as a μ-η1, η2-SbS4 tridentate bridging ligand to interlink [Ln(dien)2]3+ ions into neutral 1D coordination polymers [Ln(dien)2(μ-η1, η2-SbS4)]n, but it coordinates to the Ln3+ ions of [Ln(dien)2]3+ in 2a and 2b as a η2-SbS4 bidentate chelating ligand, leading to neutral complexes [Ln(dien)2(η2-SbS4)]. The Ln3+ ions are in 9-fold and 8-fold coordinations in Ln1 and Ln2 respectively. A systematic investigation of the crystal structures of five complexes as well as two reported compounds revealed that the soft Lewis basic ligand SbS43− coordinates to the larger lanthanide ions La3+, Ce3+, Pr3+, Nd3+, and Sm3+ as a μ-η1, η2-SbS4 tridentate bridging ligand, and to the smaller lanthanide ions Eu3+ and Dy3+ as a η2-SbS4 bidentate chelating ligand, which exhibits a lanthanide contraction effect on the coordination mode of the SbS43− ligand to the Ln3+ centers." @default.
- W1989252313 created "2016-06-24" @default.
- W1989252313 creator A5034331551 @default.
- W1989252313 creator A5037568088 @default.
- W1989252313 creator A5041164993 @default.
- W1989252313 creator A5064489538 @default.
- W1989252313 creator A5066408041 @default.
- W1989252313 creator A5075520121 @default.
- W1989252313 date "2012-01-01" @default.
- W1989252313 modified "2023-09-27" @default.
- W1989252313 title "Solvothermal syntheses and characterizations of lanthanide(iii)/SbS43− complexes associated by a dien ligand: A detailed study based on the lanthanide contraction effect" @default.
- W1989252313 cites W1533881306 @default.
- W1989252313 cites W1617446374 @default.
- W1989252313 cites W1738234301 @default.
- W1989252313 cites W1929970263 @default.
- W1989252313 cites W1963512809 @default.
- W1989252313 cites W1968512702 @default.
- W1989252313 cites W1970223651 @default.
- W1989252313 cites W1979304910 @default.
- W1989252313 cites W1991670397 @default.
- W1989252313 cites W1992821819 @default.
- W1989252313 cites W1993951375 @default.
- W1989252313 cites W2005906194 @default.
- W1989252313 cites W2012572336 @default.
- W1989252313 cites W2014197261 @default.
- W1989252313 cites W2014921249 @default.
- W1989252313 cites W2018587905 @default.
- W1989252313 cites W2024842736 @default.
- W1989252313 cites W2027512457 @default.
- W1989252313 cites W2034017956 @default.
- W1989252313 cites W2041822002 @default.
- W1989252313 cites W2047809532 @default.
- W1989252313 cites W2053589676 @default.
- W1989252313 cites W2062219106 @default.
- W1989252313 cites W2062871284 @default.
- W1989252313 cites W2068705163 @default.
- W1989252313 cites W2071632298 @default.
- W1989252313 cites W2081914790 @default.
- W1989252313 cites W2087835836 @default.
- W1989252313 cites W2087873448 @default.
- W1989252313 cites W2088374053 @default.
- W1989252313 cites W2104286063 @default.
- W1989252313 cites W2148760108 @default.
- W1989252313 cites W2174870947 @default.
- W1989252313 cites W2333973019 @default.
- W1989252313 cites W2949713447 @default.
- W1989252313 cites W2950513630 @default.
- W1989252313 cites W2950643354 @default.
- W1989252313 cites W2951798114 @default.
- W1989252313 cites W2952233770 @default.
- W1989252313 cites W2952479411 @default.
- W1989252313 cites W56537784 @default.
- W1989252313 doi "https://doi.org/10.1039/c2ce25135c" @default.
- W1989252313 hasPublicationYear "2012" @default.
- W1989252313 type Work @default.
- W1989252313 sameAs 1989252313 @default.
- W1989252313 citedByCount "16" @default.
- W1989252313 countsByYear W19892523132013 @default.
- W1989252313 countsByYear W19892523132014 @default.
- W1989252313 countsByYear W19892523132015 @default.
- W1989252313 countsByYear W19892523132016 @default.
- W1989252313 countsByYear W19892523132020 @default.
- W1989252313 crossrefType "journal-article" @default.
- W1989252313 hasAuthorship W1989252313A5034331551 @default.
- W1989252313 hasAuthorship W1989252313A5037568088 @default.
- W1989252313 hasAuthorship W1989252313A5041164993 @default.
- W1989252313 hasAuthorship W1989252313A5064489538 @default.
- W1989252313 hasAuthorship W1989252313A5066408041 @default.
- W1989252313 hasAuthorship W1989252313A5075520121 @default.
- W1989252313 hasConcept C116569031 @default.
- W1989252313 hasConcept C126322002 @default.
- W1989252313 hasConcept C145148216 @default.
- W1989252313 hasConcept C163415756 @default.
- W1989252313 hasConcept C170493617 @default.
- W1989252313 hasConcept C178790620 @default.
- W1989252313 hasConcept C185592680 @default.
- W1989252313 hasConcept C192562407 @default.
- W1989252313 hasConcept C201770740 @default.
- W1989252313 hasConcept C207991674 @default.
- W1989252313 hasConcept C21951064 @default.
- W1989252313 hasConcept C55493867 @default.
- W1989252313 hasConcept C71924100 @default.
- W1989252313 hasConceptScore W1989252313C116569031 @default.
- W1989252313 hasConceptScore W1989252313C126322002 @default.
- W1989252313 hasConceptScore W1989252313C145148216 @default.
- W1989252313 hasConceptScore W1989252313C163415756 @default.
- W1989252313 hasConceptScore W1989252313C170493617 @default.
- W1989252313 hasConceptScore W1989252313C178790620 @default.
- W1989252313 hasConceptScore W1989252313C185592680 @default.
- W1989252313 hasConceptScore W1989252313C192562407 @default.
- W1989252313 hasConceptScore W1989252313C201770740 @default.
- W1989252313 hasConceptScore W1989252313C207991674 @default.
- W1989252313 hasConceptScore W1989252313C21951064 @default.
- W1989252313 hasConceptScore W1989252313C55493867 @default.
- W1989252313 hasConceptScore W1989252313C71924100 @default.
- W1989252313 hasIssue "15" @default.
- W1989252313 hasLocation W19892523131 @default.
- W1989252313 hasOpenAccess W1989252313 @default.