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- W1989367085 abstract "[Mo(CO)2(NCS)2(dppm-PP')(dppm-P)] (dppm = Ph2PCH2PPh2) is formed in a rapid and clean redox reaction when fac- or mer-[Mo(CO)3(dppm-PP')(dppm-P)] is treated with Hg(SCN)2: dppm-chelate ring-opening with formation of a heterobimetallic species is not observed. The X-ray crystal structure of the product shows the molecule to contain seven-coordinate Mo(II) with “cis” CO groups, both monodentate and chelating dppm ligands, and with N-bonded NCS groups. The coordination geometry is intermediate between a capped trigonal prism and a capped octahedron. Crystals of [Mo(CO)2 (NCS)2(dppm-PP')(dppm-P)] are orthorhombic, space group Pna21, with a = 21.583(7) Å, b = 12.775(4) Å, c = 18.484(5) Å, and Z = 4; the final R factor was 0.046 for 3181 observed reflections." @default.
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- W1989367085 date "1987-01-01" @default.
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- W1989367085 title "Redox reaction on treating fac- or mer- [Mo(CO)3(dppm-PP')(dppm-P)] (dppm = Ph2PCH2PPh2) with Hg(SCN)2 and crystal structure of the seven-coordinate product [Mo(CO)2(NCS)2(dppm-PP')(dppm-P)]" @default.
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- W1989367085 doi "https://doi.org/10.1016/s0277-5387(00)81243-7" @default.
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