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- W1989408045 abstract "Abstract The condensed phase and matrix isolation IR and Raman spectra of antimony tribromide are reported. The solid-state spectrum comprises bands assignable to both molecular SbBr 3 and ionic SbBr 6 − species. The frequency shifts and mode sequence in the melt spectrum indicate strong dipole-dipole interactions. The matrix isolation spectra show bands of monomeric SbBr 3 and of its centrosymmetric dimer, but no features of cooperative interactions. A “bond fluctuation” explanation, previously forwarded for antimony trichloride, is considered to be further substantiated by the present findings." @default.
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- W1989408045 date "1997-01-01" @default.
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- W1989408045 title "Vibrational spectra of solid, molten and matrix isolated antimony tribromide, SbBr3" @default.
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- W1989408045 doi "https://doi.org/10.1016/s0277-5387(96)00369-5" @default.
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