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- W1989415061 abstract "A simple and efficient thiol-mediated addition of ketones to aromatic and aliphatic aldehydes is reported. This thermodynamically controlled Pummerer/aldol reaction, which can tolerate both moisture and protic functional groups, provides a direct entry to syn-β-thioketones in high chemo- and regioselectivity. Mechanistic studies revealed that selective transformation of the aldehyde to an electrophilic thionium ion species concurrent with the generation of a nucleophilic vinyl sulfide coupling partner from the ketone is imposing cross-coupling over dimerization." @default.
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- W1989415061 date "2014-11-06" @default.
- W1989415061 modified "2023-09-30" @default.
- W1989415061 title "Thiol-Promoted Selective Addition of Ketones to Aldehydes" @default.
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- W1989415061 doi "https://doi.org/10.1021/ol502937n" @default.
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